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removal from groundwater by GE-HL nanofiltration membrane: effects of arsenic concentration, pH, and co-existing

Xiaowei WANG, Wenjun LIU, Weifang MA, Desheng LI,

《环境科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 428-433 doi: 10.1007/s11783-009-0146-9

摘要： A laboratory-scale investigation was performed to study arsenic (As (V)) removal by negatively charged GE-HL nanofiltration (NF) membrane in simulated drinking water. Effects of As (V) concentration (0–200μg·L), pH, and co-ions and counter-ions were investigated. The NF membrane presented good stability, and the rejection rates exceeded 90%. The rejection rates of As (V) decreased with the increase of As (V) concentration, while it increased with the increase of pH (reached 96% at pH 6.75). Moreover, a negative relationship was observed between the co-existing ions of Cl, Na, SO, and Ca and the removal of As (V), in which bivalent ions presented more significant effects than monovalent ions.

关键词： nanofiltration (NF)     rejection rate     co-existing ion     co-ion     counter-ion    

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Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

《环境科学与工程前沿（英文）》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1581-0

摘要：

● The co-existing metals in WPCBs has positive catalytic influence in pyrolysis.

关键词： Waste printed circuit board     Catalyst     Pyrolysis     Kinetics    

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Ammonia removal from low-strength municipal wastewater by powdered resin combined with simultaneous recovery as struvite

Kuo Fang, Fei Peng, Hui Gong, Huanzhen Zhang, Kaijun Wang

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1300-7

摘要： Abstract • Powdered resin was employed for ammonia recovery from municipal wastewater. • Powdered resin achievedefficient ammonia removal under various working conditions. • Co-existing cations indicated competitive adsorption of ammonia. • Ammonia was recoveredby two-stage crystallization coupled with ion exchange. Low-strength municipal wastewater is considered to be a recoverable nutrient resource with economic and environmental benefits. Thus, various technologies for nutrient removal and recovery have been developed. In this paper, powdered ion exchange resin was employed for ammonia removal and recovery from imitated low-strength municipal wastewater. The effects of various working conditions (powdered resin dosage, initial concentration, and pH value) were studied in batch experiments to investigate the feasibility of the approach and to achieve performance optimization. The maximum adsorption capacity determined by the Langmuir model was 44.39 mg/g, which is comparable to traditional ion exchange resin. Further, the effects of co-existing cations (Ca2+, Mg2+, K+) were studied. Based on the above experiments, recovery of ammonia as struvite was successfully achieved by a proposed two-stage crystallization process coupled with a powdered resin ion exchange process. Scanning electron microscopy (SEM) and X-ray diffractometry (XRD) results revealed that struvite crystals were successfully gained in alkaline conditions (pH= 10). This research demonstrates that a powdered resin and two-stage crystallization process provide an innovative and promising means for highly efficient and easy recovery from low-strength municipal wastewater.

关键词： Ammonia removal and recovery     Powdered resin     Crystallization process     Struvite     Co-existing cations    

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Effect of co-existing organic compounds on adsorption of perfluorinated compounds onto carbon nanotubes

Shubo DENG,Yue BEI,Xinyu LU,Ziwen DU,Bin WANG,Yujue WANG,Jun HUANG,Gang YU

《环境科学与工程前沿（英文）》 2015年 第9卷 第5期   页码 784-792 doi: 10.1007/s11783-015-0790-1

摘要： Co-existing organic compounds may affect the adsorption of perfluorinated compounds (PFCs) and carbon nanotubes in aquatic environments. Adsorption of perfluorooctane sulfonate (PFOS), perfluorooctane acid (PFOA), perfluorobutane sulfonate (PFBS), and perfluorohexane sulfonate (PFH S) on the pristine multi-walled carbon nanotubes (MWCNTs-Pri), carboxyl functionalized MWCNTs (MWCTNs-COOH), and hydroxyl functionalized MWCNTs (MWCNTs-OH) in the presence of humic acid, 1-naphthol, phenol, and benzoic acid was studied. Adsorption kinetics of PFOS was described well by the pseudo-second-order model and the sorption equilibrium was almost reached within 24 h. The effect of co-existing organic compounds on PFOS adsorption followed the decreasing order of humic acid>1-naphthol>benzoic acid>phenol. Adsorbed amounts of PFOS decreased significantly in the presence of co-existing or preloaded humic acid, and both adsorption energy and effective adsorption sites on the three MWCNTs decreased, resulting in the decrease of PFOS adsorption. With increasing pH, PFOS removal by three MWCNTs decreased in the presence of humic acid and phenol. The adsorbed amounts of different PFCs on the MWCNTs increased in the order of PFBS

关键词： perfluorinated compounds     carbon nanotubes     competitive adsorption     humic acid     perfluorooctane sulfonate (PFOS)    

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A Comprehensive Evaluation of Policy Effectiveness for Energy Efficiency in Existing Buildings

Xing Wei,Han-ding Guo

《工程管理前沿（英文）》 2014年 第1卷 第4期   页码 341-347 doi: 10.15302/J-FEM-2014060

摘要： The healthy and stable development of energy efficiencies in existing buildings cannot be separated from effective policy operation, and evaluating policy effectiveness contributes to scientifically-sound government decision-making. This paper creates an evaluation index system and a grey comprehensive evaluation model for policy effectiveness for energy efficiency in existing buildings using three dimensions: 1) the effect of the policy itself; 2) the administrative effect of the policy; and 3) policy implementation effects. It chooses the government’s subsidy policy and preferential tax policy at market cultivation stage for its empirical comparative evaluation. The evaluation indicates that the former is more effective. Finally, it puts forward policy development suggestions from the perspective of: 1) clarifying incentive object; 2) broadening incentive scope; 3) increasing incentive intensity; and 4) innovating incentive mode.

关键词： grey comprehensive evaluation     existing buildings     energy efficiency     policies effectiveness    

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Discontinuous mechanical behaviors of existing shield tunnel with stiffness reduction at longitudinal

《结构与土木工程前沿（英文）》 2023年 第17卷 第1期   页码 37-52 doi: 10.1007/s11709-022-0920-3

摘要： An analytical model is proposed to estimate the discontinuous mechanical behavior of an existing shield tunnel above a new tunnel. The existing shield tunnel is regarded as a Timoshenko beam with longitudinal joints. The opening and relative dislocation of the longitudinal joints can be calculated using Dirac delta functions. Compared with other approaches, our method yields results that are consistent with centrifugation test data. The effects of the stiffness reduction at the longitudinal joints (α and β), the shearing stiffness of the Timoshenko beam GA, and different additional pressure profiles on the responses of the shield tunnel are investigated. The results indicate that our proposed method is suitable for simulating the discontinuous mechanical behaviors of existing shield tunnels with longitudinal joints. The deformation and internal forces decrease as α, β, and GA increase. The bending moment and shear force are discontinuous despite slight discontinuities in the deflection, opening, and dislocation. The deflection curve is consistent with the additional pressure profile. Extensive opening, dislocation, and internal forces are induced at the location of mutation pressures. In addition, the joints allow rigid structures to behave flexibly in general, as well as allow flexible structures to exhibit locally rigid characteristics. Owing to the discontinuous characteristics, the internal forces and their abrupt changes at vulnerable sections must be monitored to ensure the structural safety of existing shield tunnels.

关键词： tunnel–soil interaction     discontinuous analysis     longitudinal joints     existing shield tunnel     Timoshenko beam     Dirac delta function    

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Metal salts with highly electronegative cations as efficient catalysts for the liquid-phase nitration

Shenghui Zhou, Kuiyi You, Zhengming Yi, Pingle Liu, Hean Luo

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 205-210 doi: 10.1007/s11705-017-1625-3

摘要： Metal salts with highly electronegative cations have been used to effectively catalyze the liquid-phase nitration of benzene by NO to nitrobenzene under solvent-free conditions. Several salts including FeCl , ZrCl , AlCl , CuCl , NiCl , ZnCl , MnCl , Fe(NO ) ·9H O, Bi(NO ) ·5H O, Zr(NO ) ·5H O, Cu(NO ) ·6H O, Ni(NO ) ·6H O, Zn(NO ) ·6H O, Fe (SO ) , and CuSO were examined and anhydrous FeCl exhibited the best catalytic performance under the optimal reaction conditions. The benzene conversion and selectivity to nitrobenzene were both over 99%. In addition, it was determined that the metal counterion and the presence of water hydrates in the salt affects the catalytic activity. This method is simple and efficient and may have potential industrial application prospects.

关键词： metal salts     electronegativity     nitrobenzene     NO2     catalytic nitration    

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Visible light responsive photocatalysts developed by substitution with metal cations aiming at artificial

《能源前沿（英文）》 2021年 第15卷 第3期   页码 568-576 doi: 10.1007/s11708-021-0774-8

摘要： To solve resource, energy, and environmental issues, development of sustainable clean energy system is strongly required. In recent years, hydrogen has been paid much attention to as a clean energy. Solar hydrogen production by water splitting using a photocatalyst as artificial photosynthesis is a promising method to solve these issues. Efficient utilization of visible light comprised of solar light is essential for practical use. Three strategies, i.e., doping, control of valence band, and formation of solid solution are often utilized as the useful methods to develop visible light responsive photocatalysts. This mini-review introduces the recent work on visible-light-driven photocatalysts developed by substitution with metal cations of those strategies.

关键词： visible light responsive photocatalyst     water splitting     artificial photosynthesis: metal ion substitution    

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Comparison of the removal of monovalent and divalent cations in the microbial desalination cell

Shanshan CHEN,Haiping LUO,Yanping HOU,Guangli LIU,Renduo ZHANG,Bangyu QIN

《环境科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 317-323 doi: 10.1007/s11783-013-0596-y

摘要： Microbial desalination cell (MDC) is a promising technology to desalinate water and generate electrical power simultaneously. The objectives of this study were to investigate the desalination performance of monovalent and divalent cations in the MDC, and discuss the effect of ion characteristics, ion concentrations, and electrical characteristics. Mixed salt solutions of NaCl, MgCl , KCl, and CaCl with the same concentration were used in the desalination chamber to study removal of cations. Results showed that in the mixed salt solutions, the electrodialysis desalination rates of cations were: Ca >Mg >Na >K . Higher ionic charges and smaller hydrated ionic radii resulted in higher desalination rates of the cations, in which the ionic charge was more important than the hydrated ionic radius. Mixed solutions of NaCl and MgCl with different concentrations were used in the desalination chamber to study the effect of ion concentrations. Results showed that when ion concentrations of Na were one-fifth to five times of Mg , ion concentration influenced the dialysis more profoundly than electrodialysis. With the current densities below a certain value, charge transfer efficiencies became very low and the dialysis was the main process responsible for the desalination. And the phosphate transfer from the anode chamber and potassium transfer from the cathode chamber could balance 1%–3% of the charge transfer in the MDC.

关键词： divalent ion     electrodialysis     ion characteristic     microbial desalination cell     monovalent ion    

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Seismic retrofit of existing SRC frames using rocking walls and steel dampers

Akira WADA, Zhe QU, Shojiro MOTOYUI, Hiroyasu SAKATA

《结构与土木工程前沿（英文）》 2011年 第5卷 第3期   页码 259-266 doi: 10.1007/s11709-011-0114-x

摘要： A retrofit of an existing 11-story steel reinforced concrete frame that features the innovative use of post-tensioned rocking walls and shear steel dampers is presented. The main components of the retrofitting plan and important design considerations are described. The retrofitting system is expected to effectively control the deformation pattern of the existing structure and significantly reduce damage to the existing structure during major earthquakes.

关键词： building structure     seismic retrofit     rocking wall     steel damper    

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Improving existing “reaching law” for better discrete control of seismically-excited building structures

Zhijun LI, Zichen DENG

《结构与土木工程前沿（英文）》 2009年 第3卷 第2期   页码 111-116 doi: 10.1007/s11709-009-0022-5

摘要： In this paper, a novel “composite reaching law” was explained in details: 1) the equation of discrete motion for a control system; 2) the design of discrete-time variable structure control. In addition, the model of a three-storey shear-type building structure was used to verify the effectiveness of the discrete variable structure control method. The results of numerical example analysis of the model show that the control law can effectively reduce the peak value of seismic response of the building structure and the chattering effect of the control system.

关键词： discrete-time variable structure control     composite reaching law     chattering effect     saturated control law    

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既有居住建筑节能改造外部性及其量化研究

赵琰,刘晓君

《中国工程科学》 2014年 第16卷 第10期   页码 100-105

摘要：

既有商品住宅节能改造具有一定程度的外部性，阻碍了节能改造的深入开展。通过分析节能改造外部性的产生原因和外部性表现，建立外部性测算方法，为外部性内部化，构建节能改造外部性偿还机制提供必要依据。采用经济学理论与方法对既有商品住宅节能改造外部性的产生和表现等进行了分析，在识别外部性供体与受体的基础上，提出了节能改造外部性的测算方法。通过案例分析论证了外部性测算方法的适用性。结果表明，应减轻或消除外部性对节能改造的影响，采取必要手段将节能改造外部性内部化，构建统一的节能改造外部性测算方法，建立节能改造外部性偿还与节能量交易机制。

关键词： 既有商品住宅     节能改造     外部性     测算    

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Two-dimensional self-assembly of melem and melemium cations at pH-controlled aqueous solution–Au(111)

Shinobu Uemura,Kenki Sakata,Masashi Aono,Yusuke Nakamura,Masashi Kunitake

《化学科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 294-300 doi: 10.1007/s11705-016-1564-4

摘要： Two-dimensional self-assembly of melem at pH-controlled aqueous solution-Au(111) interfaces has been investigated by electrochemical scanning tunneling microscopy. In the solutions with pH>p of melem, two ordered self-assembled structures (honeycomb and close-packed structures) and one disordered fibrillar structure were observed as a function of the surface coverage of melem controlled by the electrode potential. In contrast, in the acidic solution with pH

关键词： self-assembly     scanning tunneling microscopy     electrochemistry     structural phase transition     melem    

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Surgical robotics: A look-back of latest advancement and bio-inspired ways to tackle existing challenges

Yang LIU, Jing LIU

《机械工程前沿（英文）》 2012年 第7卷 第4期   页码 376-384 doi: 10.1007/s11465-012-0352-1

摘要：

This article is dedicated to present a review on existing challenges and latest developments in surgical robotics in attempts to overcome the obstacles lying behind. Rather than to perform an exhaustive evaluation, we would emphasize more on the new insight by digesting the emerging bio-inspired surgical technologies with potentials to revolutionize the field. Typical approaches, possible applications, advantages and technical challenges were discussed. Evolutions of surgical robotics and future trends were analyzed. It can be found that, the major difficulties in the field of surgical robots may not be properly addressed by only using conventional approaches. As an alternative, bio-inspired methods or materials may shed light on new innovations. While endeavors to deal with existing strategies still need to be made, attentions should be paid to also borrow ideas from nature.

关键词： minimally invasive surgery     surgical robotics     haptic feedback     miniaturization     bio-inspiration     bionics    

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Comparative analysis of energy use in China building sector: current status, existing problems and solutions

Shengyuan ZHANG, Xiu YANG, Yi JIANG, Qingpeng WEI,

《能源前沿（英文）》 2010年 第4卷 第1期   页码 2-21 doi: 10.1007/s11708-010-0023-z

摘要： Energy use in buildings has attracted more and more attention due to its significant proportion in the energy pan of the world. China is the second largest energy user, yet the situation of energy use in the China building sector remains unclear, due to problems of statistics and data processing and problematic use of these data. In this paper, a series of methods is developed, in the first place, to give strict definitions of energy data and to divide energy use into 4 sub-sectors according to the unique situation of China. Then, each sub-sector is further analyzed through international comparisons. Existing problems of energy use and solutions for energy reduction in each sub-sector are also discussed. Accordingly, it is found that China uses much less energy, in terms of both per capita and unit area, in buildings than developed countries. The difference in energy use could be attributed, in large part, to lifestyles of local people, which could determine their way of energy use but is more determined by cultural concepts than by others such as income, technique and so on, especially in China. However, to fulfill the requirements of lifestyles with higher living standards and lower energy consumption, technological innovations are needed.

关键词： building energy use     lifestyle and technology     residential building     commercial building     rural building    

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标题 作者 时间 类型 操作

removal from groundwater by GE-HL nanofiltration membrane: effects of arsenic concentration, pH, and co-existing

Xiaowei WANG, Wenjun LIU, Weifang MA, Desheng LI,

期刊论文

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

期刊论文

Ammonia removal from low-strength municipal wastewater by powdered resin combined with simultaneous recovery as struvite

Kuo Fang, Fei Peng, Hui Gong, Huanzhen Zhang, Kaijun Wang

期刊论文

Effect of co-existing organic compounds on adsorption of perfluorinated compounds onto carbon nanotubes

Shubo DENG,Yue BEI,Xinyu LU,Ziwen DU,Bin WANG,Yujue WANG,Jun HUANG,Gang YU

期刊论文

A Comprehensive Evaluation of Policy Effectiveness for Energy Efficiency in Existing Buildings

Xing Wei,Han-ding Guo

期刊论文

Discontinuous mechanical behaviors of existing shield tunnel with stiffness reduction at longitudinal

期刊论文

Metal salts with highly electronegative cations as efficient catalysts for the liquid-phase nitration

Shenghui Zhou, Kuiyi You, Zhengming Yi, Pingle Liu, Hean Luo

期刊论文

Visible light responsive photocatalysts developed by substitution with metal cations aiming at artificial

期刊论文

Comparison of the removal of monovalent and divalent cations in the microbial desalination cell

Shanshan CHEN,Haiping LUO,Yanping HOU,Guangli LIU,Renduo ZHANG,Bangyu QIN

期刊论文

Seismic retrofit of existing SRC frames using rocking walls and steel dampers

Akira WADA, Zhe QU, Shojiro MOTOYUI, Hiroyasu SAKATA

期刊论文

Improving existing “reaching law” for better discrete control of seismically-excited building structures

Zhijun LI, Zichen DENG

期刊论文

既有居住建筑节能改造外部性及其量化研究

赵琰,刘晓君

期刊论文

Two-dimensional self-assembly of melem and melemium cations at pH-controlled aqueous solution–Au(111)

Shinobu Uemura,Kenki Sakata,Masashi Aono,Yusuke Nakamura,Masashi Kunitake

期刊论文

Surgical robotics: A look-back of latest advancement and bio-inspired ways to tackle existing challenges

Yang LIU, Jing LIU

期刊论文

Comparative analysis of energy use in China building sector: current status, existing problems and solutions

Shengyuan ZHANG, Xiu YANG, Yi JIANG, Qingpeng WEI,

期刊论文